Relaxing a Model System

relaxation protocol

Relaxation of a system is an essential part of an MD simulation, as the system that is freshly built may have a large degree of strain. Only when the system is relaxed is it useful to proceed to a production simulation, where the properties of the system at the given temperature and pressure can be analyzed.

The stages in the default relaxation process for the NPT ensemble are:

1. Simulate in the NVT ensemble with Brownian dynamics at 10 K with small time steps and solute non-hydrogen atoms restrained
2. Simulate in the NVT ensemble using a Langevin thermostat with:
  • a simulation time of 12ps
  • a temperature of 10K
  • a fast temperature relaxation constant
  • velocity resampling every 1ps
  • non-hydrogen solute atoms restrained
3. Simulate in the NPT ensemble using a Langevin thermostat and a Langevin barostat with:
  • a simulation time of 12ps
  • a temperature of 10K and a pressure of 1 atm
  • a fast temperature relaxation constant
  • a slow pressure relaxation constant
  • velocity resampling every 1ps
  • non-hydrogen solute atoms restrained
4. Simulate in the NPT ensemble using a Langevin thermostat and a Langevin barostat with:
  • a simulation time of 12 ps
  • a temperature of 300 K and a pressure of 1 atm
  • a fast temperature relaxation constant
  • a slow pressure relaxation constant
  • velocity resampling every 1ps
  • non-hydrogen solute atoms restrained
5. Simulate in the NPT ensemble using a Langevin thermostat and a Langevin barostat with:
  • a simulation time of 24ps
  • a temperature of 300K and a pressure of 1 atm
  • a fast temperature relaxation constant
  • a normal pressure relaxation constant

This protocol is used for the NPAT and NPγT ensembles as well. A similar protocol is used for the NVT ensemble.

The protocol files can be found in $SCHRODINGER/mmshare-vversion/data/desmond. The procedure follows a similar pattern as for NPT.